[N,N-Bis(diphenylphosphino)propylamine-κ2P,P]bromidotricarbonylrhenium(I)

[N,N-Bis(diphenylphosphino)propylamine-κ2P,P]bromidotricarbonylrhenium(I)

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In the title compound, [ReBr(C27H27NP2)(CO)3], the ReI atom here is octahedrally surrounded by three carbonyl ligands in a facial arrangement, a bromide ligand and the P,P′-bidentate ligand Bis(diphenylphosphino)propylamine.The compound exhibits substitutional disorder of the bromide ligand and the axial carbonyl ligand, with almost 50% occupancy for both Br amd CO [0.538 (4) and 0.

462 (4), respectively].In addition, the propyl chain on the N atom of the bidentate ligand exhibits a 0.648 (9):0.

352 (9) disorder.C—H.O and C—H.

Br ucsb gaucho blue hydrogen bonding consolidates the crystal packing.